Glucono delta-lactone

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D-Gluconic acid δ-lactone[1][2]
Glucono-delta-lactone-2D-skeletal.png
100px
Names
IUPAC name
(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-one
Other names
D-Glucono-1,5-lactone
Identifiers
90-80-2 YesY
ChEBI CHEBI:16217 YesY
ChEMBL ChEMBL1200829 N
ChemSpider 6760 YesY
DrugBank DB04564 YesY
EC Number 202-016-5
Jmol 3D model Interactive image
KEGG D04332 YesY
PubChem 736
UNII WQ29KQ9POT YesY
  • InChI=1S/C6H10O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-5,7-10H,1H2/t2-,3-,4+,5-/m1/s1 YesY
    Key: PHOQVHQSTUBQQK-SQOUGZDYSA-N YesY
  • InChI=1/C6H10O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-5,7-10H,1H2/t2-,3-,4+,5-/m1/s1
    Key: PHOQVHQSTUBQQK-SQOUGZDYBO
  • C([C@@H]1[C@H]([C@@H]([C@H](C(=O)O1)O)O)O)O
Properties
C6H10O6
Molar mass 178.14 g·mol−1
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Glucono delta-lactone (GDL), also known as gluconolactone, is a food additive with the E number E575[3] used as a sequestrant, an acidifier,[4] or a curing, pickling, or leavening agent. It is a lactone (cyclic ester) of D-gluconic acid. Pure GDL is a white odorless crystalline powder.

GDL is commonly found in honey, fruit juices, personal lubricants, and wine[citation needed]. GDL is neutral, but hydrolyses in water to gluconic acid which is acidic, adding a tangy taste to foods, though it has roughly a third of the sourness of citric acid. It is metabolized to glucose; one gram of GDL yields roughly the same amount of metabolic energy as one gram of sugar.

Upon addition to water, GDL is partially hydrolysed to gluconic acid, with the balance between the lactone form and the acid form established as a chemical equilibrium. The rate of hydrolysis of GDL is increased by heat and high pH.[5]

The yeast Saccharomyces bulderi can be used to ferment gluconolactone to ethanol and carbon dioxide. The pH value greatly affects culture growth. Gluconolactone at 1 or 2% in a mineral media solution causes the pH to drop below 3.[6]

See also

References

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  1. ↑ Lua error in package.lua at line 80: module 'strict' not found., 4469.
  2. ↑ Beil. 18, V, 5, 11
  3. ↑ Current EU approved additives and their E Numbers, Food Standards Agency
  4. ↑ Lua error in package.lua at line 80: module 'strict' not found.
  5. ↑ Lua error in package.lua at line 80: module 'strict' not found.
  6. ↑ Lua error in package.lua at line 80: module 'strict' not found.
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