Sodium arsenite
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| Names | |
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| IUPAC name
sodium arsenite
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| Other names
sodium arsenate(III)
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| Identifiers | |
7784-46-5  |
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| ChEBI | CHEBI:29678  |
| EC Number | 232-070-5 |
| Jmol 3D model | Interactive image |
| KEGG | C11906 |
| PubChem | 443495 |
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| Properties | |
| NaAsO2 | |
| Molar mass | 129.911 g/mol |
| Appearance | white or grayish powder hygroscopic |
| Density | 1.87 g/cm 3 |
| Melting point | 550 °C (1,022 °F; 823 K) decomposes |
| 156 g/100 mL | |
| Solubility | slightly soluble in alcohol |
| Vapor pressure | {{{value}}} |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Sodium arsenite usually refers to the inorganic compound with the formula NaAsO2. Also called sodium meta-arsenite, it is the sodium salt of arsenous acid. Sodium arsenite also ) Na3AsO3, called sodium ortho-arsenite.[1] The compounds are colourless solids.
Synthesis and structure
A mixture of sodium meta-arsenite and sodium ortho-arsenite is produced by treating arsenic trioxide with sodium carbonate or sodium hydroxide.[2] Sodium arsenite is amorphous, typically being obtained as a powder or as a glassy mass. The compound consists of the polymer [AsO2]n−
n associated with sodium cations, Na+. The polymer backbone has the connectivity -O-As(O−)-.[3]
Health Effects
Sodium arsenite can be inhaled or absorbed through the skin. Along with its known carcinogenic and teratogenic effects, contact with the substance can yield symptoms such as skin irritation, burns, itching, thickened skin, rash, loss of pigment, poor appetite, a metallic or garlic taste, stomach pain, nausea, vomiting, diarrhea, convulsions, decreased blood pressure, and headache. Severe acute poisoning may lead to nervous system damage resulting in weakness, poor coordination, or “pins and needles” sensations, eventual paralysis, and death.[4][5]
Application
It is primarily used as a pesticide, but has other uses such as hide preservative, antiseptic, dyeing, and soaps.[6]
Sodium arsenite is an appropriate chemical stressor to induce production of heat shock proteins.[7]
Safety
The LD50 (oral, mouse) is 40 mg/kg.[2]
References
- ↑ Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.
- ↑ 2.0 2.1 Lua error in package.lua at line 80: module 'strict' not found.
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- ↑ New Jersey Department of Health and Senior Services. Hazardous Substance Fact Sheet: Sodium Arsenite [1] (2013-05-01)
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
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